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有色金属工程:2019,9(6):-
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碳酸钙对污染土壤中Pb、Zn、Cd的稳定化作用
张湘茗, 任学昌
(兰州交通大学 环境与市政工程学院)
Stabilization Effects of Calcium Carbonate for Pb, Zn and Cd in Contaminated Soil
ZHANG Xiangming, REN Xuechang
(Lanzhou Jiaotong University,School of Environmental and Municipal Engineering)
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投稿时间:2018-08-02    修订日期:2018-08-15
中文摘要: 为了探究碳酸钙对污染土壤中Pb、Zn、Cd的稳定化作用,以甘肃省白银东大沟Pb、Zn、Cd等重金属复合污染土壤为研究对象,通过添加不同质量的碳酸钙进行稳定化实验,结果表明:在轻度污染土壤中,当CaCO3的添加量由1%增加至15%时,pH由初始7.45升高至7.91,浸出浓度降低;用水平振荡法浸出时,Pb、Zn的稳定效率最大分别达到50.75%、51.18%;用硫酸硝酸法浸出时,Pb、Zn的稳定效率最大分别达到55.19%、21.40%。在重度污染土壤中,当CaCO3的添加量由2%增加至18%时,pH由初始6.76升高至7.16,浸出浓度降低;用水平振荡法浸出时,Pb、Zn、Cd的稳定效率最大分别达到75.82%、74.21%、99.19%;用硫酸硝酸法浸出时,Pb、Zn、Cd的稳定效率最大分别达到26.75%、65.55%、78.39%。添加碳酸钙后土壤pH略有升高是由于CaCO3在土壤溶液中溶解产生OH-,土壤中的重金属通过形成氢氧化物和碳酸盐沉淀,从而有效降低了重金属的迁移性,起到重金属的稳定化作用。
中文关键词: 碳酸钙  重金属  污染土壤  稳定化
Abstract:To explore stabilization effects of calcium carbonate for Pb, Zn and Cd in contaminated soil, taking heavy metal (such as Pb, Zn and Cd) compound contaminated soils in Baiyin Dongdagou of Gansu province as research object, adding different amounts of calcium carbonate conducted stabilization experiments. The results show that the pH increased from original 7.45 to 7.91 and the leaching concentration decreased gradually; the stabilization efficiency of Pb, Zn reached maximumly 50.75% 、51.18% respectively with horizontal vibration method and 55.19%、21.40% respectively with sulphuric acid & nitric acid method when the addition amount of calcium carbonate were increased from 1% to 15% in lightly contaminated soil. The pH increased from original 6.76 to 7.16 and the leaching concentration decreased gradually; the stabilization efficiency of Pb, Zn and Cd reached maximumly 75.82%、74.21%、99.19% respectively with horizontal vibration method and 26.75%、65.55%、78.39% respectively with sulphuric acid & nitric acid method when the addition amount of calcium carbonate were increased from 2% to 18% in the heavily contaminated soil. The slight increasing of pH after adding calcium carbonate is that calcium carbonate will dissolve and generate OH- in soil solution, heavy metals may be formed?hydroxide and carbonate precipitation, thus reduced effectively the migration of heavy metals and had the stabilization of heavy metals.
文章编号:     中图分类号:X53    文献标志码:
基金项目:兰州交通大学优秀平台基金Lzjtu(201606)支撑;国家自然科学(51268026);国家自然科学(51068016)
引用文本:
张湘茗,任学昌.碳酸钙对污染土壤中Pb、Zn、Cd的稳定化作用[J].有色金属工程,2019,9(6):.

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