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有色金属工程:2020,(3):-
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硫化技术在重金属固废综合利用方面的研究
贺壮志1, 何晓娟2, 陈志强2, 刘勇2, 饶金山2, 吕昊子2
(1.中南大学 资源加工与生物工程学院;2.广东省资源综合利用研究所)
The Research on Sulfidation Technology in Comprehensive Utilization of Heavy Metal Solid Waste:A Review
hezhuangzhi1, hexiaojuan2, chenzhiqiang2, liuyong2, raojinshan2, lvhaozi2
(1.Central South University School of Minerals Processing and Bioengineering;2.Guangdong Institute of Resource Comprehensive Utilization)
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本文已被:浏览 2197次   下载 1814
投稿时间:2019-02-19    修订日期:2019-03-14
中文摘要: 重金属固废的综合利用价值较高,但是当前综合利用技术处于实验室水平较多,工业可行性较低;参考“硫化-浮选”工艺,重金属的硫化技术成为该工艺能否在固废综合利用方面应用的关键。本文在介绍了表面硫化技术、机械硫化技术、水热硫化技术、硫化沉淀技术和硫化焙烧技术及其在天然矿物方面应用的基础上,总结硫化技术在重金属固废(废渣、飞灰和污泥为主)综合利用方面的适用性和研究进展;进一步讨论五种硫化技术在重金属固废综合利用方面的优缺点,指出针对不同理化性质的固废应选择不同的硫化技术;最后得出硫化技术的发展方向为明确硫化物的晶体和表面性质等和可浮性之间的关系,明确硫化率的影响因素,掌握硫化物晶体结构和表面性质的调控技术。
Abstract:The comprehensive utilization value of heavy metal solid waste is relatively high, but the industrialization feasibility of comprehensive utilization technologies developed in laboratory is relatively low. Referring to the “sulfidation-flotation” process, the sulfidation technology of heavy metals is the key to whether the process can be applied in the comprehensive utilization of solid waste. Based on the introduction of surface sulfidation, mechanical sulfidation, hydrothermal sulfidation, sulfidation precipitation, sulfidation roasting technology and their application in natural minerals, this paper summaries the applicability and research status of the five sulfidation technologies in the comprehensive utilization of heavy metal solid waste(mainly including waste residue, fly ash and plating sludge). Further, the article discusses the advantages and disadvantages of the five sulfidation technologies, and pointed out that different sulfidation technologies should be selected for solid waste with different physical and chemical properties; Finally, the article concludes that the development direction of sulfidation technology is to clarify the relationship between the sulfide properties and floatability, determine the influencing factors of sulfidation rate, and master the control technology of sulfide crystal structure and surface properties.
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基金项目:广东省科技计项目划2017B090904035、2017A070701020,广东省科学院创性能力建设专项 2017GDASCX—0109
引用文本:
贺壮志,何晓娟,陈志强,刘勇,饶金山,吕昊子.硫化技术在重金属固废综合利用方面的研究[J].有色金属工程,2020,(3):.

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