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投稿时间:2021-02-01 修订日期:2021-03-15
投稿时间:2021-02-01 修订日期:2021-03-15
中文摘要: 为比较磷酸钠与磷酸二氢钠对铅污染土壤的稳定化效果,本研究采用了国内两种标准方法—《固体废物浸出毒性浸出方法 水平振荡法》(HJ 557-2010)和《固体废物浸出毒性浸出方法 醋酸缓冲溶液法》(HJT 300-2007)浸提不同添加比例(P:Pb=3:1、P:Pb=8:1 (摩尔比))、不同培养时间(7天、20天、30天)条件下磷酸钠、磷酸二氢钠稳定的两种(HN、YN)铅污染土壤。醋酸缓冲溶液法浸提结果表明,磷酸钠、磷酸二氢钠对土壤中铅具有良好的稳定化效果,培养至第30天时,添加磷酸钠且P:Pb=8:1时,与对照组相比,可提取态铅浓度降低了96.8%。水平振荡法浸提结果表明,相较于对照组,添加磷酸钠、磷酸二氢钠使土壤中可提取态铅浓度增加,且磷酸钠各添加比例在YN、HN组的水平振荡法可提取态铅浓度均比磷酸二氢钠各添加比例的浓度高。培养至第30天时,添加磷酸钠且P:Pb=8:1时,可提取态铅浓度达3.72mg/L。在本试验研究条件下,两种浸提方法在7-30天内可提取态铅浓度趋势不同,醋酸缓冲溶液法可提取态铅浓度呈降低趋势,而水平振荡法可提取态铅浓度呈上升趋势。添加磷酸钠、磷酸二氢钠使得土壤中水平振荡法提取态铅浓度增加,对重金属铅污染土壤具有一定风险性,且磷酸钠作为土壤铅污染修复剂比磷酸二氢钠风险高。
Abstract:To compare the stabilizing effects of sodium phosphate and sodium dihydrogen phosphate on lead-contaminated soil. This study used two domestic standard methods—"Solid waste-Extraction procedure for leaching toxicity-Horizontal vibration method"(SELH) (HJ 557-2009) and Solid waste-Extraction procedure for leaching toxicity-Acetic acid buffer solution method" (SELA)(HJT 300-2007).Using the above two methods to extract two kinds of lead-contaminated soil,which are stable with phosphate amendments(Na3PO4,NaH2PO4) was employed at a 3 and 8 P/Pb molar ratio in different incubation time(day:7,20,30). The SELA-Pb results show that Na3PO4 and NaH2PO4 amendment significantly reduced Pb mobilization. At the 30th day of culture, Na3PO4 was employed at a 8 P/Pb molar ratio, compared with the control group, SELA-Pb was reduced by 96.8%. The extraction results of SELH-Pb showed that the addition of Na3PO4 and NaH2PO4 increased the concentration of extractable lead in the soil compared to the control group, and addition of Na3PO4 in the YN and HN groups had a higher concentration of SELH-PB than addition of NaH2PO4. At the 30th day of culture, Na3PO4 was employed at a 8 P/Pb molar ratio, SELH-PB reached 3.72 mg/L. Under the conditions of this experiment, the two extraction methods have different extractable lead concentration trends within 7-30 days. The extractable lead concentration of the acetate buffer solution method shows a decreasing trend, while the horizontal shaking method extracts the lead concentration shows an upward trend. The addition of Na3PO4 and NaH2PO4increases the concentration of lead extracted by the horizontal shaking method in the soil, which has a certain risk to heavy metal lead contaminated soil, and Na3PO4 as a soil lead pollution remediation agent has a higher risk than NaH2PO4.
keywords: Na3PO4 NaH2PO4 Soil lead pollution SELH SELA
文章编号: 中图分类号: 文献标志码:
基金项目:中国科学院A类战略性先导科技专项项目
作者 | 单位 | |
陈龙 | 中国科学院大学资源与环境学院 | chenlong18@mails.ucas.edu.cn |
王淑平* | 中国科学院大学资源与环境学院 | wshuping@ucas.ac.cn |
崔岩山 | 中国科学院大学资源与环境学院 | |
刘小茼 | 中国科学院大学资源与环境学院 |
引用文本:
陈龙,王淑平,崔岩山,刘小茼.基于国内两种标准比较磷酸钠与磷酸二氢钠对铅污染土壤的稳定化效果[J].有色金属工程,2021,(9):.
陈龙,王淑平,崔岩山,刘小茼.基于国内两种标准比较磷酸钠与磷酸二氢钠对铅污染土壤的稳定化效果[J].有色金属工程,2021,(9):.