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投稿时间:2021-06-04 修订日期:2021-06-22
投稿时间:2021-06-04 修订日期:2021-06-22
中文摘要: 以市售的A2B7型La-Mg-Ni系储氢合金作为负极材料并分别加入Y2O3、La2O3、ZnO和MgO作为添加剂制作AA1500型镍氢电池,并对其放电容量、充电态内阻、自放电、循环寿命和过充性能进行了测试与分析。结果表明:添加Y2O3和La2O3的电池在0.2C倍率下的放电容量与未添加电池基本一致,而以MgO和ZnO作为添加剂制作的电池容量比未添加的低7.2mAh和17.1mAh;负极添加剂的加入不同程度的提高了电池的内阻;但加入添加剂制作的电池自放电性能均有不同程度的提高,添加MgO制作的电池55℃储存7天后荷电保持率最好达到80.1%;添加Y2O3和La2O3与未添加制作的电池具有较好的耐过充性能;添加Y2O3制作的电池的循环寿命得到明显提高,循环200次后容量保持率提高至86.19%。
Abstract:AA1500 type Ni-MH batteries were prepared by using commercially available A2B7 type La-Mg-Ni hydrogen storage alloy as negative electrode material, and adding Y2O3, La2O3, ZnO and MgO as additives. The discharge capacity, internal resistance of charging state, self-discharge, cycle life and overcharge performance of the battery were tested and analyzed. The results showed that the discharge capacity of the batteries with Y2O3 and La2O3 at 0.2C discharge rate was much the same as that of the batteries without the addition of Y2O3 and La2O3, while the discharge capacity of the batteries with MgO and ZnO as additives was 7.2mAh and 17.1mAh lower than that of batteries without the addition of MgO and ZnO, respectively. The addition of negative electrode additive increased the internal resistance of the battery. However, the self-discharge performance of the battery made by adding additives was improved to varying degrees. The charge retention rate of the batteries prepared by adding MgO can still reach 80.1% after 7 days storage at 55 C. The addition of Y2O3 and La2O3 had better overcharge resistance than that of batteries not added. The cycle life of batteries made by adding Y2O3 was significantly improved, and the capacity retention rate reached 86.19% after 200 cycles.
keywords: MH-Ni battery additive capacity self-discharge cycle life
文章编号: 中图分类号:TM912.2 文献标志码:
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引用文本:
李宝犬,徐津,王利,闫慧忠.负极添加剂对镍氢电池性能的影响[J].有色金属工程,2022,(4):7-12.
李宝犬,徐津,王利,闫慧忠.负极添加剂对镍氢电池性能的影响[J].有色金属工程,2022,(4):7-12.