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投稿时间:2023-10-30 修订日期:2023-11-09
投稿时间:2023-10-30 修订日期:2023-11-09
中文摘要: 为了防止SiC颗粒与过渡金属在高温下混合应用时发生反应,使用流化床PECVD在名义粒度80目SiC颗粒表面镀覆完整的Al2O3隔绝膜。通过扫描电子显微镜、X射线衍射仪等对膜层的形态、组成和物相进行了表征,利用混合烧结法模拟SiC颗粒与过渡金属在高温下混合应用的状态。膜层厚度在4微米以上,膜层主要成分为无定形氧化铝,和少量含碳杂质。在700 ℃/1060 ℃的温度和空气氛围中保温12小时,膜层发生相变,生成γ-Al2O3/α-Al2O3。经高温真空腐蚀实验验证,证实膜层有效防止SiC与Ni等过渡金属反应,提高了SiC颗粒高温应用的性能。
Abstract:In order to stop reaction between silicon carbide particle and transition metals in high temperature, this research introduces a new core-shell material consisting of 80 mesh SiC particle and uniform alumina insulation layer, which is made by fluidized bed plasma enhanced chemical vapor deposition (FB-PECVD) method. The morphology, composition and phase structure of the coating were characterized by scanning electron microscope and X-ray diffractometer. The mixed sintering method was conducted to simulate the state of SiC particles mixed with transition metals at high temperatures. The alumina layer is 4 μm thick and is made of amorphous alumina with little carbonaceous impurities. After 12-hrs calcination at 700 ℃/1060 ℃ in air, the amorphous alumina layer transform to γ-Al2O3/α-Al2O3 layer. After high-temperature vacuum calcination, this insulation layer effectively prevents SiC particle from reaction with Ni-alloy metal material, resulting in better performance of SiC in high temperature.
keywords: Fluidized bed PECVD alumina coating insulating film
文章编号:YSJSGC20230630 中图分类号:TB332 文献标志码:
基金项目:
作者 | 单位 | |
郭睿* | 北矿新材科技有限公司 | guorui@bgrimm.com |
刘建明 | 北矿新材科技有限公司 | liu_jm@bgrimm.com |
黄凌峰 | 北矿新材科技有限公司 | huanglingfeng@bgrimm.com |
王帅 | 北矿新材科技有限公司 | wangshuai@bgrimm.com |
引用文本:
郭睿,刘建明,黄凌峰,王帅.SiC颗粒包覆氧化铝隔绝膜性能研究[J].有色金属工程,2024,14(3):.
郭睿,刘建明,黄凌峰,王帅.SiC颗粒包覆氧化铝隔绝膜性能研究[J].有色金属工程,2024,14(3):.